DSC analysis of dissolution reaction in an as-cast and HPT-processed Mg-Gd alloy

Authors: Hanna, A., Azzeddine, H., Avettand-Fènoël, M.N., Baudin, T., Huang, Y. and Langdon, T.G.

Journal: Materials Letters

Volume: 376

eISSN: 1873-4979

ISSN: 0167-577X

DOI: 10.1016/j.matlet.2024.137293

Abstract:

The dissolution reaction kinetics were determined by differential scanning calorimetry (DSC) analysis for Mg-0.6Gd (wt.%) in an as-cast condition and after processing by high-pressure torsion (HPT) at room temperature for 20 turns. For the as-cast condition, the dissolution temperature was in the range of 634–658 K with an activation energy of 135 ± 9 kJ/mol. After HPT, the range of dissolution temperature decreased to 601–633 K, with a lower activation energy of 118 ± 10 kJ/mol. In both conditions, the Avrami and growth exponents are around 1.5, which suggests that the dissolved precipitates exhibit polyhedron-like morphology and that the dissolution process is dominated by bulk dissolution with a constant rate controlled by diffusion.

https://eprints.bournemouth.ac.uk/40267/

Source: Scopus

DSC analysis of dissolution reaction in an as-cast and HPT-processed Mg-Gd alloy

Authors: Hanna, A., Azzeddine, H., Avettand-Fenoel, M.-N., Baudin, T., Huang, Y. and Langdon, T.G.

Journal: MATERIALS LETTERS

Volume: 376

eISSN: 1873-4979

ISSN: 0167-577X

DOI: 10.1016/j.matlet.2024.137293

https://eprints.bournemouth.ac.uk/40267/

Source: Web of Science (Lite)

DSC analysis of dissolution reaction in an as-cast and HPT-processed Mg-Gd alloy

Authors: Hanna, A., Azzeddine, H., Avettand-Fènoël, M.-N., Baudin, T., Huang, Y. and Langdon, T.G.

Journal: Materials Letters

Volume: 376

Pages: 137293(1)-137293(4)

Publisher: Elsevier

ISSN: 0167-577X

DOI: 10.1016/j.matlet.2024.137293

Abstract:

The dissolution reaction kinetics were determined by differential scanning calorimetry (DSC) analysis for Mg-0.6Gd (wt.%) in an as-cast condition and after processing by high-pressure torsion (HPT) at room temperature for 20 turns. For the as-cast condition, the dissolution temperature was in the range of 634–658 K with an activation energy of 135±9 kJ/mol. After HPT, the range of dissolution temperature decreased to 601–633 K, with a lower activation energy of 118±10 kJ/mol. In both conditions, the Avrami and growth exponents are around 1.5, which suggests that the dissolved precipitates exhibit polyhedron-like morphology and that the dissolution process is dominated by bulk dissolution with a constant rate controlled by diffusion.

https://eprints.bournemouth.ac.uk/40267/

Source: Manual

Preferred by: Yi Huang

DSC analysis of dissolution reaction in an as-cast and HPT-processed Mg-Gd alloy

Authors: Hanna, A., Azzeddine, H., Avettand-Fènoël, M.-N., Baudin, T., Huang, Y. and Langdon, T.G.

Journal: Materials Letters

Volume: 376

Publisher: Elsevier

ISSN: 0167-577X

Abstract:

The dissolution reaction kinetics were determined by differential scanning calorimetry (DSC) analysis for Mg-0.6Gd (wt.%) in an as-cast condition and after processing by high-pressure torsion (HPT) at room temperature for 20 turns. For the as-cast condition, the dissolution temperature was in the range of 634–658 K with an activation energy of 135±9 kJ/mol. After HPT, the range of dissolution temperature decreased to 601–633 K, with a lower activation energy of 118±10 kJ/mol. In both conditions, the Avrami and growth exponents are around 1.5, which suggests that the dissolved precipitates exhibit polyhedron-like morphology and that the dissolution process is dominated by bulk dissolution with a constant rate controlled by diffusion.

https://eprints.bournemouth.ac.uk/40267/

Source: BURO EPrints