A new and highly selective turn-on fluorescent sensor with fast response time for the monitoring of cadmium ions in cosmetic, and health product samples
Authors: Khani, R., Ghiamati, E., Boroujerdi, R., Rezaeifard, A. and Zaryabi, M.H.
Journal: Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
Volume: 163
Pages: 120-126
ISSN: 1386-1425
DOI: 10.1016/j.saa.2016.03.011
Abstract:Cadmium (Cd) which is an extremely toxic could be found in many products like plastics, fossil fuel combustion, cosmetics, water resources, and wastewaters. It is capable of causing serious environmental and health problems such as lung, prostate, renal cancers and the other disorders. So, the development of a sensor to continually monitor cadmium is considerably demanding. Tetrakis(4-nitrophenyl)porphyrin, T(4-NO2-P)P, was synthesized and used as a new and highly selective fluorescent probe for monitoring cadmium ions in the "turn-on" mode. There was a linear relationship between fluorescence intensity and the concentration of Cd(II) in the range of 1.0 × 10- 6 to 1.0 × 10- 5 mol L- 1 with a detection limit of 0.276 μM. To examine the most important parameters involved and their interactions in the sensor optimization procedure, a four-factor central composite design (CCD) combined with response surface modeling (RSM) was implemented. The practical applicability of the developed sensor was investigated using real cosmetic, and personal care samples.
Source: Scopus
A new and highly selective turn-on fluorescent sensor with fast response time for the monitoring of cadmium ions in cosmetic, and health product samples.
Authors: Khani, R., Ghiamati, E., Boroujerdi, R., Rezaeifard, A. and Zaryabi, M.H.
Journal: Spectrochim Acta A Mol Biomol Spectrosc
Volume: 163
Pages: 120-126
eISSN: 1873-3557
DOI: 10.1016/j.saa.2016.03.011
Abstract:Cadmium (Cd) which is an extremely toxic could be found in many products like plastics, fossil fuel combustion, cosmetics, water resources, and wastewaters. It is capable of causing serious environmental and health problems such as lung, prostate, renal cancers and the other disorders. So, the development of a sensor to continually monitor cadmium is considerably demanding. Tetrakis(4-nitrophenyl)porphyrin, T(4-NO2-P)P, was synthesized and used as a new and highly selective fluorescent probe for monitoring cadmium ions in the "turn-on" mode. There was a linear relationship between fluorescence intensity and the concentration of Cd(II) in the range of 1.0×10(-6) to 1.0×10(-5)molL(-1) with a detection limit of 0.276μM. To examine the most important parameters involved and their interactions in the sensor optimization procedure, a four-factor central composite design (CCD) combined with response surface modeling (RSM) was implemented. The practical applicability of the developed sensor was investigated using real cosmetic, and personal care samples.
Source: PubMed
A new and highly selective turn-on fluorescent sensor with fast response time for the monitoring of cadmium ions in cosmetic, and health product samples
Authors: Khani, R., Ghiamati, E., Boroujerdi, R., Rezaeifard, A. and Zaryabi, M.H.
Journal: SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
Volume: 163
Pages: 120-126
eISSN: 1873-3557
ISSN: 1386-1425
DOI: 10.1016/j.saa.2016.03.011
Source: Web of Science (Lite)
A new and highly selective turn-on fluorescent sensor with fast response time for the monitoring of cadmium ions in cosmetic, and health product samples.
Authors: Khani, R., Ghiamati, E., Boroujerdi, R., Rezaeifard, A. and Zaryabi, M.H.
Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy
Volume: 163
Pages: 120-126
eISSN: 1873-3557
ISSN: 1386-1425
DOI: 10.1016/j.saa.2016.03.011
Abstract:Cadmium (Cd) which is an extremely toxic could be found in many products like plastics, fossil fuel combustion, cosmetics, water resources, and wastewaters. It is capable of causing serious environmental and health problems such as lung, prostate, renal cancers and the other disorders. So, the development of a sensor to continually monitor cadmium is considerably demanding. Tetrakis(4-nitrophenyl)porphyrin, T(4-NO2-P)P, was synthesized and used as a new and highly selective fluorescent probe for monitoring cadmium ions in the "turn-on" mode. There was a linear relationship between fluorescence intensity and the concentration of Cd(II) in the range of 1.0×10(-6) to 1.0×10(-5)molL(-1) with a detection limit of 0.276μM. To examine the most important parameters involved and their interactions in the sensor optimization procedure, a four-factor central composite design (CCD) combined with response surface modeling (RSM) was implemented. The practical applicability of the developed sensor was investigated using real cosmetic, and personal care samples.
Source: Europe PubMed Central